Organic compounds with functional groups containing nitrogen
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March 04, 2016 |
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Organic compounds with
functional groups containing nitrogen
Objectives
1.Introduction nitro compounds
2.Nomenclature
3.Structure and physical properties
4.Preparation of nitro compounds
5.Chemical reactions
6.Cyanides and isocyanides
General method of preparation
Physical and chemical properties
7. Diazo
compounds
General method of preparation
Physical and chemical properties
Preparation of nitro
compounds
1.Aliphatic nitro compounds
Vapour phase nitration of alkanes
Treatment of alkyl halides with alcoholic AgNO3
Oxidation of t-alkyl amines with KMnO4.
2. Aromatic nitro compounds
Vapour phase nitration of alkanes
Hydrocarbons on
heating with fuming nitric acid at 693-793 K are converted into nitroalkanes.
This method is
important in the commercial production of nitro compounds.
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